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Ver Investigador - - Prisma - Unidad de Bibliometría

Rafael Andreu Fondacabe

Investigador Honorario
fondacab@us.es
Área de conocimiento: Química Física
Departamento: Química Física
Grupo: CINÉTICA ELECTRÓDICA E INSTRUMENTACIÓN - FQM-128 (Universidad de Sevilla)
Prog. doctorado: ELECTROQUÍMICA. CIENCIA Y TECNOLOGÍA (INTERUNIVERSITARIO)

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Líneas de investigación
Resumen
Tipo Año Título Fuente
Artículo2022 Electric field-induced functional changes in electrode-immobilized mutant species of human cytochrome c. BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS
Artículo2022 Enzyme-like activity of cobalt-MOF nanosheets for hydrogen peroxide electrochemical sensing SENSORS AND ACTUATORS B-CHEMICAL
Artículo2021 Active role of the buffer in the proton-coupled electron transfer of immobilized iron porphyrins INORGANIC CHEMISTRY
Artículo2021 Highly sensitive hydrogen peroxide biosensor based on tobacco peroxidase immobilized on p-Phenylenediamine diazonium cation grafted carbon nanotubes: preventing fenton-like inactivation at negative potential ChemElectroChem
Revisión2021 Immobilizing redox enzymes at mesoporous and nanostructured electrodes CURRENT OPINION IN ELECTROCHEMISTRY
Artículo2021 Structural and functional insights into lysine acetylation of cytochrome c using mimetic point mutants. FEBS OPEN BIO
Ponencia2020 Effect of phosphorylation on the redox functionality of human cytochrome C Recent progress on electrochemistry at the Iberian Peninsula: proceeding book of the XL Meeting of the Specialized Group of Electrochemistry of the Royal Spanish Society of Chemistry and the XX Iberian Meeting of Electrochemistry (Huelva, 9th to 12th July 2019)
Artículo2020 Influence of tryptophan mutation on the direct electron transfer of immobilized tobacco peroxidase ELECTROCHIMICA ACTA
Artículo2020 Physical contact between cytochrome c1 and cytochrome c increases the driving force for electron transfer BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS
Artículo2019 The Fe (III)/Fe(II) redox couple as a probe of immobilized tobacco peroxidase: Effect of the immobilization protocol ELECTROCHIMICA ACTA
Artículo2018 Highly sensitive, stable and selective hydrogen peroxide amperometric biosensors based on peroxidases from different sources wired by Os-polymer: A comparative study SOLID STATE IONICS
Artículo2018 Key Role of the Local Hydrophobicity in the East Patch of Plastocyanins on Their Thermal Stability and Redox Properties ACS OMEGA
Artículo2018 Protein crosslinking improves the thermal resistance of plastocyanin immobilized on a modified gold electrode BIOELECTROCHEMISTRY
Artículo2018 Proton transfer impedance of electrodes modified with acid thiol monolayers JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2017 A Comparative Study between Hydrogen Peroxide Amperometric Biosensors Based on Different Peroxidases Wired by Os-Polymer: Applications in Water, Milk and Human Urine Proceedings (MDPI)
Revisión2017 Intermolecular interactions in electroactive thiol monolayers probed by linear scan voltammetry CURRENT OPINION IN ELECTROCHEMISTRY
Artículo2016 Fenton-like Inactivation of Tobacco Peroxidase Electrocatalysis at Negative Potentials ACS CATALYSIS
Artículo2016 Super-Nernstian Shifts of Interfacial Proton-Coupled Electron Transfers: Origin and Effect of Noncovalent Interactions JOURNAL OF PHYSICAL CHEMISTRY C
Artículo2015 Interprotein Coupling Enhances the Electrocatalytic Efficiency of Tobacco Peroxidase Immobilized at a Graphite Electrode ANALYTICAL CHEMISTRY
Artículo2014 Potentiostatic infrared titration of 11-mercaptoundecanoic acid monolayers ELECTROCHEMISTRY COMMUNICATIONS
Artículo2014 Temperature-Driven Changeover in the Electron-Transfer Mechanism of a Thermophilic Plastocyanin JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Artículo2013 Analytical Expressions for Proton Transfer Voltammetry: Analogy to Surface Redox Voltammetry with Frumkin Interactions ANALYTICAL CHEMISTRY
Artículo2012 Diffusional Surface Voltammetry as a Probe of Adsorption Energetics ANALYTICAL CHEMISTRY
Artículo2012 Proton Transfer Voltammetry at Electrodes Modified with Acid Thiol Monolayers ANALYTICAL CHEMISTRY
Artículo2012 Voltammetric study of the adsorbed thermophilic plastocyanin from Phormidium laminosum up to 90 degrees C ELECTROCHEMISTRY COMMUNICATIONS
Artículo2011 Accurate Analytical Expressions for Stripping Voltammetry in the Henry Adsorption Limit ANALYTICAL CHEMISTRY
Artículo2011 Chemical Reactivity and Electrochemistry of Metal-Metal-Bonded Zincocenes INORGANIC CHEMISTRY
Artículo2010 Aliphatic Alcohols Facilitate Interfacial Reorientation of Thiols: Correlation with Alcohol Adsorptivity LANGMUIR
Artículo2010 Probing interfacial solvation of incipient self-assembled monolayers PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Artículo2010 Reorientation of Thiols during 2D Self-Assembly: Interplay between Steric and Energetic Factors LANGMUIR
Artículo2008 Direct electron transfer from graphite and functionalized gold electrodes to T1 and T2/T3 copper centers of bilirubin oxidase BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS
Artículo2008 Potential of zero charge as a sensitive probe for the titration of ionizable self-assembled monolayers ELECTROCHEMISTRY COMMUNICATIONS
Artículo2007 Determination of the potential of zero charge of Au(111) modified with thiol monolayers ANALYTICAL CHEMISTRY
Artículo2007 Direct electron transfer kinetics in horseradish peroxidase electrocatalysis JOURNAL OF PHYSICAL CHEMISTRY B
Artículo2007 Electro-oxidation of altertoxin I (ATX-I) at gold electrodes modified by dodecanethiol self-assembled monolayers JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2007 Folding and unfolding in the blue copper protein rusticyanin: Role of the oxidation state BIOINORGANIC CHEMISTRY AND APPLICATIONS
Artículo2006 Onset of crystalline order in 1-nonanethiol monolayers deposited from solution ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Artículo2005 Calculation of ionic surface excess concentrations in the diffuse double layer at low field strengths for a restricted primitive model electrolyte JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2005 Electrochemical formation and electron transfer through self-assembled monolayers of 4-mercaptophenol on mercury JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2005 Experimental study of the interplay between long-range electron transfer and redox probe permeation at self-assembled monolayers: Evidence for potential-induced ion gating JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo2004 Improvement of alternariol monomethyl ether detection at gold electrodes modified with a dodecanethiol self-assembled monolayer JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2004 The electrocapillary effect at an electrode modified with an insoluble redox-active self-assembled monolayer LANGMUIR
Artículo2003 Analysis of the diffuse layer potential drop in the limit of small fields on the basis of a generalized mean spherical approximation JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2003 Influence of temperature on the reduction kinetics of Zn2+ at a mercury electrode JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2003 Kinetic analysis of wired enzyme electrodes. Application to horseradish peroxidase entrapped in a redox polymer matrix JOURNAL OF PHYSICAL CHEMISTRY B
Ponencia2003 Monte Carlo simulation of diffuse layer properties. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
Artículo2002 Voltammetry of surface redox processes perturbed by dimerization and adsorption of the products - Application to the oxidation of 3-mercaptoprapanol on mercury JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Artículo2001 A kinetic model for the reductive desorption of self-assembled thiol monolayers LANGMUIR
Artículo2001 An isotropic model for micellar systems: Application to sodium dodecyl sulfate solutions LANGMUIR
Artículo2001 Application of the unequal distances of closest approach theory to the analysis of double-layer effects on Zn(II) reduction at a mercury electrode JOURNAL OF PHYSICAL CHEMISTRY A
Artículo2001 Formation and reductive desorption of mercaptohexanol monolayers on mercury JOURNAL OF PHYSICAL CHEMISTRY B
Artículo2001 Influence of spatial redox distribution on the electrochemical behavior of electroactive self-assembled monolayers JOURNAL OF PHYSICAL CHEMISTRY B
Artículo2000 Quantitative characterization of desorptive stripping voltammograms complicated by surface dimerization reactions. Application to the reductive desorption of thiols from mercury JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2000 Reduction mechanism of deoxybenzoin on a mercury electrode JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo2000 Voltammetry of surface redox processes perturbed by a father-son reaction ELECTROCHIMICA ACTA
Artículo1999 Comparison of cationic excesses in the presence of perchlorate and chloride anions LANGMUIR
Artículo1999 Influence of adsorption/diffusion coupling on surface voltammetric waves. First stages of 2-mercaptoethanesulfonate oxidative adsorption on gold LANGMUIR
Artículo1999 Voltammetry of surface electrodimerization processes. Application to the oxidation of adsorbed 2-mercaptoethyl ether on mercury LANGMUIR
Artículo1997 Discreteness of charge and ion association effects on electroactive self-assembled monolayers LANGMUIR
Artículo1997 Reduction mechanism of benzoin on a mercury electrode JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1997 Role of ion pairing in double-layer effects at self-assembled monolayers containing a simple redox couple JOURNAL OF PHYSICAL CHEMISTRY B
Artículo1996 Application of the MPB theory to the analysis of the ion-free layer thickness ELECTROCHIMICA ACTA
Artículo1996 Desorption of spontaneously adsorbed and electrochemically readsorbed 2-mercaptoethanesulfonate on Au(111) LANGMUIR
Artículo1996 Numerical simulation of desorption transients at electrodes on the basis of non-linear adsorption isotherms JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS
Artículo1996 The role of the metal in determining electrosorption valency in the case of strong molecular adsorption at the electrode vertical bar solution interface JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Letter1995 A sniftirs study of the double-layer at a gold electrode in dimethylacetamide Journal of physical chemistry
Artículo1995 Influence of solution acidity on the adsorption and charge-transfer kinetics of parabanic acid reduction JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1995 Numerical-simulation of bulk electrolysis in the presence of homogeneous following reactions Journal of physical chemistry
Artículo1994 Discreteness-of-charge effects at molecular films containing acid/base groups Journal of physical chemistry
Artículo1994 On the simultaneous evaluation of charge-transfer kinetics and adsorption - reduction of parabanic acid in low acidity x M HCl + (2 - x)M LiCl mixtures JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1993 Adsorption of malonate and succinate at the hg/aqueous solution interphase JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1993 Generalization of the udca theory and its application to the analysis of the ion-free layer thickness JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1992 A comparative-study of the interphase between mercury and aqueous-solutions of monovalent, divalent and trivalent chlorides JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1991 An automatic system for the measurement of dropping mercury-electrode impedances ELECTROANALYSIS
Artículo1991 Electrochemical reduction of benzil in strongly acid and alkaline media JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1990 Keto-enol-tautomerism in the electrochemical reduction of parabanic acid JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1990 Kinetic salt effects in intramolecular electron-transfer JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS
Artículo1989 A comparative-study of the adsorption of la-3+ and al-3+ at the mercury aqueous-electrolyte interphase JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Nota1989 Ion size effects in the hurwitz-parsons analysis - allowance for a lower dielectric-constant between the 2 cationic ohps JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1986 Adsorption of chloride at the mercury aqueous lacl3 interface JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1986 Adsorption of crotonaldehyde at the mercury water interface JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1986 The reduction of cr(III) in concentrated aqueous-electrolytes at a DME - the influence of anions JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1985 Ionpit - a full implementation of pitzers ion interaction treatment Computers & Chemistry
Artículo1985 Voltametric determination of standard rate-constant and formal potential of the couple CR-3+/CR-2+ in NACLO4 ANALES DE QUIMICA SERIE A-QUIMICA FISICA Y QUIMICA TECNICA
Artículo1984 Adsorption of cinnamaldehyde at the mercury-water interface JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1984 The catalysis of the reduction of zn(II) ions by iodide-ions - a mechanistic study in mixed 1-m naclo4/nai aqueous-solutions JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1984 The reduction of cr3+ in naclo4 solutions JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Ponencia1983 New trend in the study of charge transfer reactions using the combination of first and second order ac techniques Extended Abstracts, Meeting - International Society of Electrochemistry
Artículo1982 The mechanism of the reduction of zn(ii) from naclo4 base electrolyte-solutions at the dme JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Artículo1978 Voltammetry of gold electrode in buffered and unbuffered aqueous-solutions Anales de Química
Efectos salinos en cinetica electrodica (1982)
Dirigida por: Jan Sluyters
Tesis dirigidas/tutorizadas:5
Fecha lectura Título Rol
22/07/2013 ESTUDIO ELECTROQUÍMICO DE MONOCAPAS AUTOENSAMBLADAS IONIZABLES Director/a, Tutor/a
14/03/2008 TRANSFERENCIA Y ALMACENAMIENTO DE CARGA EN MONOCAPAS AUTOEMSAMBLADAS DE TIOLES Director/a
24/09/1999 Voltametría de procesos redox con adsorción de los productos. Aplicación al estudio de la adsorción oxidativa de los organotioles sobre oro y mercurio Director/a
01/01/1995 Estudio del acoplamiento de los procesos de adsorción, transferencia electrónica y cinética homogénea en la reducción electroquímica del ácido parabánico Director/a
01/01/1988 Estudio de la Interfase entre mercurio y disoluciones acuosas de LaCl3 y AlCl3 Director/a

Proyectos de Investigación

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
01/11/2002 31/10/2005 Responsable Autoensamblado y optimización de sistemas electroquímicos integrados (BQU2002-02603) Ministerio de Ciencia y Tecnología (Nacional)
07/04/2000 06/10/2001 Responsable Desarrollo de un sistema automatizado de análisis de los efluentes de una planta de clorosa (PTR1995-0432-OP) Ministerio de Educación, Cultura y Deporte (Nacional)
31/01/2008 31/12/2012 Responsable Estudio y Optimización de la Velocidad de Intercambio Electrónico Entre Enzimas y Electrodos (P07-FQM-02492) Junta de Andalucía - Consejería de Innovación, Ciencia y Empresas (Autonómico)
31/12/2005 31/12/2008 Investigador/a Estudio de sistemas bioelectroquímicos nanoestructurados (CTQ2005-01184) Ministerio de Educación y Ciencia (Nacional)
01/01/2009 30/06/2013 Investigador/a Electroquímica de plataformas biomiméticas estratificadas (CTQ2008-00371) Ministerio de Ciencia e Innovación (Nacional)
01/01/2015 31/12/2018 Responsable Acoplamiento de Procesos de Transferencia de Carga y Reorganización Molecular en Sistemas Electroquímicos Biomiméticos (CTQ2014-52641-P) Ministerio de Economía y Competitividad (Nacional)
01/09/2022 31/08/2025 Investigador/a Racionalización de los Factores que Regulan la Transferencia de Carga y Catálisis en Bioelectrodos (PID2021-126799NB-I00) Ministerio de Ciencia e Innovación (Nacional)
01/12/2022 30/09/2025 Investigador/a Conversión de energía renovables en productos químicos mediante la producción de H2 acoplada con la captura y conversión de CO2 (TED2021-130191B-C42) Ministerio de Ciencia e Innovación (Nacional)
El investigador no tiene ningún resultado de investigación asociado