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Ver Investigador - - Prisma - Unidad de Bibliometría

María del Carmen Nicasio Jaramillo

Catedrática de Universidad
mnicasio@us.es
Área de conocimiento: Química Inorgánica
Departamento: Química Inorgánica
Grupo: Estructura y reactividad de compuestos organometálicos. Catálisis Homogénea. - FQM-382 (Universidad de Sevilla)
Prog. doctorado: QUÍMICA

Investiga en

Palabras clave
Líneas de investigación
Resumen
Tipo Año Título Fuente
Capítulo2024 Developing Ni and Pd precatalysts for demanding cross-coupling reactions Advances in Inorganic Chemistry
Artículo2024 Microkinetic Model as a Crucial Tool for Understanding Homogeneous Catalysis CHEMCATCHEM
Artículo2024 Ni‐Catalyzed [2+2+2] Cycloaddition of Alkynes to Form Arenes and Pyridines at Low Catalyst Loadings ADVANCED SYNTHESIS & CATALYSIS
Artículo2023 Broad-Scope Amination of Aryl Sulfamates Catalyzed by a Palladium Phosphine Complex ACS CATALYSIS
Artículo2023 Important role of NH-carbazole in aryl amination reactions catalyzed by 2-aminobiphenyl palladacycles ACS CATALYSIS
Artículo2023 Synthesis and characterization of enantiopure chiral NH2/SO palladium complexes ORGANIC & BIOMOLECULAR CHEMISTRY
Artículo2022 A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation CHEMICAL COMMUNICATIONS
Artículo2022 LPdCl2(amine) complexes supported by terphenyl phosphanes: applications in aryl amination reactions DALTON TRANSACTIONS
Artículo2021 N-substituted aminobiphenyl palladacycles stabilized by dialkylterphenyl phosphanes: preparation and applications in C[sbnd]N cross-coupling reactions INORGANICA CHIMICA ACTA
Artículo2021 Ni(II) precatalysts enable thioetherification of (hetero)aryl halides and tosylates and tandem C-S/C-N couplings. CHEMISTRY-A EUROPEAN JOURNAL
Artículo2021 Zero-valent ML2 complexes of group 10 metals supported by terphenyl phosphanes CHEMICAL COMMUNICATIONS
Editorial2020 Breaking bonds over many timescales: In celebration of Robin Perutz's 70th birthday DALTON TRANSACTIONS
Artículo2020 Dialkylterphenyl phosphine-based palladium precatalysts for efficient aryl amination of N-nucleophiles CHEMISTRY-A EUROPEAN JOURNAL
Artículo2020 Dinuclear Cu(I) Halides with Terphenyl Phosphines: Synthesis, Photophysical Studies, and Catalytic Applications in CuAAC Reactions INORGANIC CHEMISTRY
Capítulo2020 Low-coordinate M(0) complexes of group 10 stabilized by phosphorus(III) ligands and N-heterocyclic carbenes ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 68
Artículo2019 Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo2019 Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines DALTON TRANSACTIONS
Artículo2019 Synthesis, Structure and Nickel Carbonyl Complexes of Dialkylterphenyl Phosphines CHEMISTRY-A EUROPEAN JOURNAL
Artículo2018 Elucidating the Mechanism of Aryl Aminations Mediated by NHC-Supported Nickel Complexes: Evidence for a Nonradical Ni(0)/Ni(II) Pathway ACS CATALYSIS
Artículo2017 Phosphine-functionalized NHC Ni(II) and Ni(0) complexes: synthesis, characterization and catalytic properties DALTON TRANSACTIONS
Artículo2016 Ni-Catalyzed Amination Reactions: An Overview CHEMICAL RECORD
Artículo2015 C-N Coupling of Indoles and Carbazoles with Aromatic Chlorides Catalyzed by a Single-Component NHC-Nickel(0) Precursor ADVANCED SYNTHESIS & CATALYSIS
Revisión2015 Copper-catalysed azide-alkyne cycloadditions (CuAAC): an update ORGANIC & BIOMOLECULAR CHEMISTRY
Artículo2014 1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap CHEMICAL COMMUNICATIONS
Artículo2014 Reaction of alkynes and azides: Not triazoles through copper-acetylides but oxazoles through copper-nitrene intermediates CHEMISTRY-A EUROPEAN JOURNAL
Artículo2014 Synthesis, Structural Characterization, Reactivity, and Catalytic Properties of Copper(I) Complexes with a Series of Tetradentate Tripodal Tris(pyrazolylmethyl)amine Ligands INORGANIC CHEMISTRY
Artículo2013 Silver-catalyzed silicon-hydrogen bond functionalization by carbene insertion DALTON TRANSACTIONS
Artículo2012 Copper(I) Complexes with Trispyrazolylmethane Ligands: Synthesis, Characterization, and Catalytic Activity in Cross-Coupling Reactions INORGANIC CHEMISTRY
Ponencia2012 Kumada coupling of heteroaromatic chlorides and aryl ethers catalyzed by [(IPr)Ni(allyl)Cl] complex ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
Artículo2012 Kumada-Tamao-Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl ORGANIC LETTERS
Ponencia2012 Oxazol synthesis: A novel route through copper-catalyzed reactions of 1-alkynes and acylazides ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
Artículo2012 Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)(2) in the Amination of Aryl Tosylates ORGANOMETALLICS
Artículo2011 Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo2010 Copper(I) complexes as catalysts for the synthesis of N-sulfonyl-1,2,3-triazoles from N-sulfonylazides and alkynes ORGANIC & BIOMOLECULAR CHEMISTRY
Libro2010 Libro de comunicaciones Libro de comunicaciones
Artículo2010 Well-Defined Allylnickel Chloride/N-Heterocyclic Carbene [(NHC)Ni(allyl)Cl] Complexes as Highly Active Precatalysts for C-N and C-S Cross-Coupling Reactions ADVANCED SYNTHESIS & CATALYSIS
Artículo2009 Dinuclear Copper(I) Complexes as Precatalysts in Ullmann and Goldberg Coupling Reactions ORGANOMETALLICS
Artículo2009 Hydrotrispyrazolylborate-copper complexes as catalysts for the styrene cyclopropanation reaction with ethyl diazoacetate under homogeneous and heterogeneous conditions INORGANICA CHIMICA ACTA
Artículo2009 Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T DALTON TRANSACTIONS
Artículo2007 Catalytic carbon-hydrogen bond functionalization in an ionic liquid medium ORGANOMETALLICS
Artículo2007 Synthesis, characterization, and reactivity of ruthenium Diene/Diamine complexes including catalytic hydrogenation of ketones INORGANIC CHEMISTRY
Artículo2006 The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: no classical C-H activation, but efficient C-H functionalization DALTON TRANSACTIONS
Artículo2006 Very efficient, reusable copper catalyst for carbene transfer reactions under biphasic conditions using ionic liquids ORGANIC LETTERS
Artículo2005 Functionalization of primary carbon-hydrogen bonds of alkanes by carbene insertion with a silver-based catalyst ORGANOMETALLICS
Artículo2004 Alkane dehydrogenation by sequential, double C-H bond activation by Tp(Br3)Ir(C2H4)(2) (Tp(Br3) = hydrotris(3,4,5-tribromo)pyrazolylborate) ORGANOMETALLICS
Artículo2004 Complete control of the chemoselectivity in catalytic carbene transfer reactions from ethyl diazoacetate: An N-heterocyclic carbene-Cu system that suppresses diazo coupling JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo2004 Copper-homoscorpionate complexes as very active catalysts for the olefin aziridination reaction ORGANOMETALLICS
Artículo2004 Reaction of ethyl diazoacetate with alkyl-aromatic substrates: Influence of the Tp(x)Cu catalyst in the addition versus insertion chemoselectivity (Tp(x) = homoscorpionate) ORGANOMETALLICS
Artículo2003 Copper-catalyzed carbene insertion into O-H bonds: High selective conversion of alcohols into ethers ORGANOMETALLICS
Artículo2003 Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst Tp(Br3)Cu(NCMe) JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo2003 Functionalization of carbon-hydrogen bonds of hydrocarbons and ethers via carbene insertion with copper(I)-homoscorpionate catalysts ORGANOMETALLICS
Artículo2003 Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo2002 Catalytic insertion of diazo compounds into N-H bonds: the copper alternative CHEMICAL COMMUNICATIONS
Artículo2002 Copper(I)-homoscorpionate catalysts for the preferential, kinetically controlled cis cyclopropanation of alpha-olefins with ethyl diazoacetate JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo2002 Intermolecular copper-catalyzed carbon-hydrogen bond activation via carbene insertion JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo2002 Intramolecular dealkylation of chelating diamines with Ru(II) complexes CHEMICAL COMMUNICATIONS
Artículo2001 A family of highly active copper(I)-homoscorpionate catalysts for the alkyne cyclopropenation reaction CHEMICAL COMMUNICATIONS
Artículo2000 From homogeneous to heterogeneous catalysis: Novel anchoring of polypyrazolylborate copper(I) complexes on silica gel through classical and nonclassical hydrogen bonds. Use as catalysts of the olefin cyclopropanation reaction ORGANOMETALLICS
Artículo2000 Novel (methyl)- and (acetyl)palladium complexes containing bis(pyrazolyl)borate ligands - Dynamic equilibrium between eta(2) and eta(1) forms for the complex Bp*(Me)(PCy3)Pd [Bp* = dihydridobis(3,5-dimethylpyrazolyl)borate] EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Artículo2000 Substitution and hydrogenation reactions on rhodium(I)-ethylene complexes of the hydrotris(pyrazolyl)borate ligands Tp ' (Tp ' = Tp, Tp(Me2)) INORGANIC CHEMISTRY
Artículo1999 Kinetics of the BpCu-catalyzed carbene transfer reaction (Bp equals dihydridobis(1-pyrazolyl)borate). Is a 14-electron species the real catalyst for the general copper-mediated olefin cyclopropanation? ORGANOMETALLICS
Artículo1998 BpCu-catalyzed cyclopropanation of olefins: A simple system that operates under homogeneous and heterogeneous conditions (Bp=dihydridobis(pyrazolyl)borate) ORGANOMETALLICS
Artículo1998 C-H bond activation of benzene and cyclic ethers by TpIr(III) species CHEMISTRY-A EUROPEAN JOURNAL
Artículo1998 Organometallic derivatives of Ni(II) with poly(pyrazolyl)borate ligands JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo1998 Photochemistry of Os(dmpe)(2)H-2: Matrix, transient solution, and NMR studies of 16-electron Os(dmpe)(2) (dmpe = Me2PCH2CH2PMe2) ORGANOMETALLICS
Artículo1998 Synthesis and characterisation of rhodium(I) complexes containing the dihydrobis(pyrazolyl)borate ligands [H2B(pz ')(2)](-). The X-ray structures of Bp*Rh(C2H4)(2) and BpRh(PPh3)(2) (Bp = H2B(pz)(2); Bp* = H2B(3,5-Me-2-pz)(2) INORGANICA CHIMICA ACTA
Artículo1998 Vinylic C-H bond activation and hydrogenation reactions of Tp ' Ir(C2H4)(L) complexes INORGANIC CHEMISTRY
Revisión1997 Formation of hydrido-eta(3)-allyl complexes of Ir-III by sequential olefinic C-H bond activation and C-C coupling of alkenyl and olefin ligands CHEMISTRY-A EUROPEAN JOURNAL
Artículo1997 Synthesis and reactivity of new palladium alkyl complexes containing PMe3 ligands: Insertion reactions and formation of bis(pyrazolyl) borate derivatives JOURNAL OF ORGANOMETALLIC CHEMISTRY
Artículo1997 Transient photochemistry, matrix isolation, and molecular structure of cis-Ru(dmpm)(2)H-2 (dmpm equals Me(2)PCH(2)PMe(2)) ORGANOMETALLICS
Artículo1995 Laser flash-photolysis and matrix-isolation studies of ru[r(2)pch(2)ch(2)pr(2)](2)h-2 (r=c2h5, c6h5, c2f5) - control of oxidative addition rates by phosphine substituents JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Nota1994 An ir(iii) compound that thermally activates 2 molecules of c6h6 and forms a stable dinitrogen complex JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo1994 Ylide and allyl complexes of nickel derived from the tetranuclear alkylidene [Ni2(Mu)2-ChCMe2-O-C6H4)Cl(PMe3)2]2 Gazzetta Chimica Italiana
Artículo1993 Alkylidenes by alpha-h abstraction from metallacycles - synthesis and characterization of alkylidene-bridged complexes of nickel ORGANOMETALLICS
Artículo1993 Dialkyl complexes of nickel(ii) containing chelating diphosphines - the crystal-structure of [ni(ch2sime2ph)2(ipr2pch2ch2pipr2)] JOURNAL OF ORGANOMETALLIC CHEMISTRY
Nota1992 Double carbon-hydrogen activation at the .alpha.-carbon of cyclic ethers by Tp*Ir(C2H4)2 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Artículo1992 Monohapto coordination of poly(tert-butylpyrazolyl)borate ligands in nickel and palladium complexes JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Contribucion a la quimica organometalica de los elementos niquel, paladio e iridio (1993)
Dirigida por: Ernesto Carmona Guzmán
Tesis dirigidas/tutorizadas:9
Fecha lectura Título Rol
06/10/2023 Paladaciclos mononucleares con ligandos terfenil fosfinas: síntesis, estructuras y aplicaciones catalíticas Tutor/a, Director/a
07/07/2023 Complejos de níquel con ligandos dialquilterfenil fosfinas. Aplicaciones catalíticas en reacciones de ciclotrimerización de alquinos y de acoplamiento cruzado Tutor/a, Director/a
08/07/2021 Reactivity of Quadruply Bonded Dimolybdenum Hydride Centres: Elementary Organometallic Reactions and Coordination to Main-Group Metal-Carbon and Metal-Hydrogen Bonds Director/a, Tutor/a
11/09/2020 PALLADIUM COMPLEXES STABILIZED BY DIALKYLTERPHENYL PHOSPHINE LIGANDS. APPLICATIONS IN BUCHWALD-HARTWIG AMINATION REACTIONS Director/a, Tutor/a
06/06/2019 SYNTHESIS, STRUCTURE AND REACTIVITY OF DIALKYL TERPHENYL PHOSPHINE COMPLEXES OF LATE TRANSITION METALS Director/a, Tutor/a
25/06/2013 Desarrollo de nuevos sistemas catalíticos para la formación de enlaces C-C, C-N, C-S y C-Si Director/a
12/03/2011 Desarrollo de sistemas catalíticos para las relaciones de cicloadición [3+2] de alquinos y azidas y de adición e inserción de nitrenos Director/a
11/12/1983 Desarrollo de sistemas catalíticos basados en cobre para reacciones de formación de enlaces C-N, C-S y C-O Director/a
2004 Síntesis, caracterización estructural y aplicaciones catalíticas de complejos de Ru(II) con ligandos nitrogenados: reacciones de inserción de carbenos en enlaces X-H (X = C, N, O) catalizadas por complejos de Cu(I) con ligados de tipo homoescorpionato Director/a

Proyectos de Investigación

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
05/10/2021 31/03/2023 Responsable Formación catalítica de enlaces C-C y C-heteroátomo. Búsqueda de soluciones sostenibles y nuevas metodologías (P20_00624) Consejería de Economía, Conocimiento, Empresas y Universidad (Autonómico)
01/09/2021 31/12/2024 Responsable Estrategias catalíticas para la formación de enlaces carbono-carbono y carbono-heteroátomo en estructuras hidrocarbonadas (PID2020-113797RB-C22) Ministerio de Ciencia e Innovación (Nacional)
01/01/2018 31/07/2021 Responsable Desarrollo de Sistemas Catalíticos y Estequimétricos Basados en Metales de Transición para la Funcionalización de Enlaces Carbono Hidrógeno de Hidrocarburos y sus Derivados (CTQ2017-82893-C2-2-R) Ministerio de Economía y Competitividad (Nacional)
01/02/2020 30/04/2022 Responsable Complejos de bajo número de coordinación de metales del grupo 10 (Ni, Pd y Pt) con ligandos fosforados voluminosos. Aplicaciones en catálisis. (US-1262266) Junta de Andalucía (Consejería de Economía y Conocimiento) (Autonómico)
01/01/2015 31/12/2017 Responsable Valorización de Materias Primas Asequibles: Desarrollo de Sistemas Basados en Metales para la Activación y Funcionalización de Dióxido de Carbono, Hidrocarburos y Dinitrógeno. (CTQ2014-52769-C3-3-R) Ministerio de Economía y Competitividad (Nacional)

Infraestructura

Fecha de inicio Fecha de fin Rol Denominación Agencia financiadora
01/01/2016 30/06/2018 Responsable Equipamiento científico para la Unidad de Química Organometálica del Departamento de Química Inorgánica de la Universidad de Sevilla (UNSE15-CE-3005) Ministerio de Economía y Competitividad (Europeo)
01/01/2018 31/12/2020 Responsable Equipamiento científico para la Unidad de Química Organometálica y Catálisis Homogénea del Departamento de Química Inorgánica de la Universidad de Sevilla (EQC2018-004352-P) Ministerio de Ciencia, Innovación y Universidades - Agencia Estatal de Investigación (Nacional)
El investigador no tiene ningún resultado de investigación asociado